Chapter 12:
Gases and Their Properties12.1 THE PROPERTIES OF GASES
millimeters of mercury (mm Hg) - sometimes called the torr, at sea level the pressure is 760 mm Hg or 760 torrs.
pascal (Pa) - defined in terms of force per unit area.
1 pascal (Pa) = 1 newton/meter2
Often the kilopascal (kPa) is more often used as it is larger.
bar - the equivalent of 100,000 Pa.
Unit Relationships
1 atm = 760 mm Hg = 101.325 kPa = 1.013 bar
12.2 GAS LAWS: THE EXPERIMENTAL BASIS
compressibility - gases have no fixed volume.
Boyle's Law - the volume of a fixed amount of gas at a given temperature is inversely proportional to the pressure exerted by the gas.
P = CB * 1/V or PV = CB
Charles's Law - if a given quantity of gas is held at a constant pressure, its volume is directly proportional to the Kelvin temperature.
V = CC * T or CC = V/T
general gas law / combined gas law - the volume of a gas is inversely proportional to its pressure at constant temperature and directly proportional to the Kelvin temperature at constant pressure.
P1 V1 / T1 = P2 V2 / T2
Gay-Lussac's law of combining volumes - the ratio of the volumes of gases in a reaction was always a small whole number, as long as the volumes are measured at the same temperature and pressure.
Avogadro's hypothesis - equal volumes of gas under the same conditions of temperature and pressure have equal numbers of molecules.
Avogadro's Law - the volume of a gas, at a given temperature and pressure, is directly proportional to the quantity of gas.
V = CA * n
12.3 THE IDEAL GAS LAW
gas constant (R) - a constant used to interrelate the properties of any gas. R = 0.082057 L*atm / K*mol.
ideal gas law - describes the behavior of an ideal gas.
PV = nRT
standard temperature and pressure (STP) - Temperature of 273.15 K and a pressure of 1 atm.
standard molar volume - one mol of gas at STP occupies 22.414 L.
Density of Gases
d = m/V = PM/RT